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There are lots of non chemical options, but it really depends on how the heavy cream is used in the recipe. There is a non-hydrogeneated toffuti sour cream that works decently as a sour cream, but it needs a bit of tinkering. I have a lot of recipes on my site (www.couldntbeparve.com) that use healthy substitutes in recipes that commonly use cream like ice cream and panna cotta. If you have a specific recipe that you want to convert to non-dairy feel free to send it to me and I will help think of creative ways to do it.
There is a product called MimicCreme, packaged in an aseptic quart, made from nuts. It appears to have been formulated for food service use, and is meant to mimic cream -- it's pretty heavy!
Mimiccreme is great in some recipes, but it does have a noticeable nutty taste which may not be desirable depending on the recipe you are trying to make.
for sour cream, I'd use greek yogurt. Heavy cream may be more difficult to sub.
Plain non-dairy yogurt works for sour cream, for something like a coffee cake you can add a teaspoon or two of lemon to room temperature soy milk (or other non-dairy "milk" product) and let it sit until it starts to curdle and use that (in the way you might sub buttermilk for sour cream or yogurt in a baking recipe).
For heavy cream I often use the thick cream at the top of a can of coconut milk.