If you sprinkle chopped nuts on top of the batter, they will toast perfectly during baking time and it saves you a step! Plus picky eaters can easily scrape them off :)
By all means toast them. 350 degrees until fragrant, then roughly chop with a knife. Toasting them not only adds another layer of flavor to your brownies, but it also gives them a pleasant texture, unlike the "pencil eraser" texture of untoasted nuts.
You don't have to toast them first, but if you do, the oils will brown a bit and taste toastier. So, yes, I'd toast them, just to add another dimension of flavor to the brownies.
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