Genius Recipes
The Crispiest Roasted Potatoes, Thanks to One Little Step
How Molly Yeh wins the Super Bowl.

From our new podcast network, The Genius Recipe Tapes is lifelong Genius hunter Kristen Miglore’s 10-year-strong column in audio form, featuring all the uncut gems from the weekly column and video series. Subscribe on Apple Podcasts, Spotify, or wherever you get your podcasts so you don’t miss out.
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Now why did I do this? Well, I find a lot of the time, the food bloggers here on Food52 are not very well informed on food science or chemistry. Ms. Miglore does not mention the NaHCO3 trick in her introduction, maybe because neither she nor the staff probably do not know that raising the pH of things like potatoes, dry beans, and a lot of vegetables when cooking in water breakdowns the pectin in the vegetable tissues that hold plants together. The second thing is the high Na+ titer in the cooking water accelerates ion exchange of sodium ions for calcium and magnesium ions in the pectin, analogous to what happens when one regenerates a water softener column with salt. Net, net, you get a lot more surface gelatinization of the potato starch this way.
This high pH treatment causes things like potatoes to develop a very grainy, rough surface texture, which is ideal for browning either in the oven or by frying. Try it sometime, with something like duck fat roasted potatoes, for example, which are prepared much the same way as in this recipe, but with duck fat in lieu of butter. Every time I make d.f.r.p., our family all but licks the platter clean.
But my pinch of NaHCO3 was not the reason I am panning this recipe. Not at all.
You see, I prepared this dish hours ahead of time and had a large room temperature bowl of wonderfully browned and tasty potato cubes (when warm, that is). A jar of the paprika mayonnaise prepared exactly as per the recipe was chilled in the refrigerator prior to combining with the room temperature roasted potatoes just before serving at our family Easter banquet.
The dish reminded me and some of the guests at our Easter dinner of cold French fries with dressing. And that Ladies and Gentlemen is why I would not make this again unless I can serve it hot or at least warm.
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