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I want to only frost inbetween each layer, leaving the rainbow edges visible. But right now, they are turning out brownish-red, orange, etc. Less time in the oven? Lower temp? Butter instead of pam for no sticking?
The only solution I can think of is to trim the browned edges off with a bread knife, good luck!
Sadassa_Ulna suggestion is the best answer.
If you want to up the ante; Cut out a hole..in the center of the cake..maybe pressing a tall thin 'energy drink' type can tin sniped off with shears down to remove a 'core' from the center. Trim the edges as mentioned above beforehand and cut the 'doughnut' of the cake in half.
Results---"two rainbow" cakes.
I find that parchment lining, when pulled off, leaves more of the cake "inside" versus a crust. so you might try lining the SIDES of your cake pan with a strip of parchment paper. I'd think that butter would cause more browning on the cake sides