A little back story here; piri piri dates back to the days when the Portuguese had colonies in West Africa---sometimes it's known as pili pili. Myself, I think that in addition to chicken it goes well the Brasilian/Portugese hybrid stew, feijoada. Great as well with porco a Alentejana---sizzling hot pork and clams. Do you like goat? It's great with that too.
Besides the above answers, you could throw it in tomato sauce and toss pasta in it. Or use the same sauce and make pizza/flatbread (with complimentary toppings, or not, and just use the sauce for a spicy kick).
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