susanne - i just realized you must be about to make the chili recipe i suggested. GOOD LUCK! hope you like it. here is the michael chiarello recipe that inspired it. perhaps you will want to add back in some of the things i omitted or changed.
my whole foods carries the the "bobs red mill" brand.
pretty sure it's with the oats and grains and cereals to cook, not necessarily the flour. good luck! otherwise, maybe order online.
here: http://www.amazon.com/Bobs-Red-Mill-Harina-24-ounces/dp/B001HTIT9C
Susanne, check out one of the Mexican groceries in the Italian Market on 9th St -- they definitely carry Masa Harina. Try Tortilleria San Roman (where fresh hot tortillas are $2 a kilo!) -- if they don't have it they can certainly tell you where to go.
In a pinch, you can use packaged corn tortillas (ripped/ground up into tiny pieces) in place of masa harina. The toritillas are made from masa harina and water. I think the 1TB of masa in the recipe is meant to be a thickener, so you should be ok using tortillas.
I've done that to thicken soups before, with success, but some of the corn tortillas may need to be whirled in the blender unless you are cooking for a long time, where they should fall apart.
If you can't find it in the Mexican aisle of your local supermarket and you don't have a Mexican grocery store nearby, you can substitute an equal amount of fine corn meal. Not much difference between the two in that application -- but if you purchase the masa, you can make tortillas to serve with the chili.
Try any grocery catering to the Hispanic community. Also, Whole Foods definitely carries it. (Masa harina is basically finely ground cornmeal; it's not quite the same as the plain stuff, but if you're not making tortillas, you can probably substitute fine cornmeal.)
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http://www.foodnetwork.com/recipes/michael-chiarello/chiarello-chocolate-chili-con-carne-recipe/index.html
pretty sure it's with the oats and grains and cereals to cook, not necessarily the flour. good luck! otherwise, maybe order online.
here: http://www.amazon.com/Bobs-Red-Mill-Harina-24-ounces/dp/B001HTIT9C
http://www.food52.com/recipes/7880_short_rib_chili