I once heard someone describing a very complicated and multi-step recipe, with a "what crazy person would do that?" tone of voice. Of course was thinking, I would. Hence the lupini beans--see my previous pickle topic.
But now I can ask before I jump in. Who has made homemade bitters, and have you done it more than once?
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I pour Bourbon over vanilla beans, let it sit a while, and it works well as vanilla extract.
http://www.youtube.com/watch?v=Wr03xICTlDk
Other things to try: vanilla extract, limoncello, or vanilla sugar.
I tried making homemade vanilla extract once - turned into a science experiment-gone-bad. Good luck!